Is the LL.B earned as post graduate degree?

Howdy:

I've been investigating the careers of some characters in my novel. My
brother earned a Ph.D in Law after he graduated from college with a
bachelor's degree. Is this how it is in England?
I can't tell. The literature implies six years of college, but
it isn't clear if you must already have a bachelor's or if the LL.B is
instead of a bachelor's. Are they Ph.D's? ie are the
lawyers doctors of law?

Thank you for any help!
I'm an engineer that's never been to the UK, but sometimes my
characters must work there.

.

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