Separation of Organic Mixture.

Dear All,
I want to separate a mixture for purification purposes in my
laboratory. The components of the mixture are as below along with their
freezing/melting points.
1. Tributyl Phosphate (-79 degree Celcius)
2. Dibutyl Phosphate (-15 degree Celcius)
3. Monobutyl Phosphate (Not known)
4. Water (0 degree C)
5. n-Butanol (-90 degree Celcius)
Is it possible to separate dibutyl phosphate from the rest of the
mixture by freezing the solution to about -30 degree celcius (which can
be achieved by a mixture of crushed ice and hydrated calcium chloride)?
An alternate way is to distill but it is an azeotropic distillation
which require a lot of energy and effort. Waiting for your precious
replies.
Regards,
Atta.

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